I assume that the power supply is plugged into a jack right? If so, take the PS out of the jack, and given that your data sheet says pin positive you should shove the red meter probe inside the barrel connector and you can hold the black (negative) probe on the outside of the barrel. Unloaded you'll probably read a little higher than 24V, but that's not really a concern. Alternatively you could just measure across any of the power supply caps, I think that should yield half the power supply voltage since those caps are after the TLE splits the voltage. That might be a good check anyway to see if the TLE is doing its job correctly.